The Three States
| State | Particle Arrangement | Shape | Volume |
|---|---|---|---|
| Solid | Close, ordered, vibrate in place | Fixed | Fixed |
| Liquid | Close, random, can slide past each other | Not fixed (takes container shape) | Fixed |
| Gas | Far apart, move freely and fast | Not fixed | Not fixed |
Particle (Kinetic) Model
All matter is made of tiny particles in constant motion. Higher temperature → faster particles → more kinetic energy.
Phase Changes
Heating or cooling material can change its state:
Solid → Liquid : melting
Liquid → Gas : evaporation / boiling
Gas → Liquid : condensation
Liquid → Solid : freezing/solidification
Solid → Gas : sublimation (e.g. dry ice)
Gas → Solid : deposition
During a phase change the temperature stays constant even though energy is being added or removed. The energy goes into breaking (or forming) bonds between particles.
Latent Heat
Q = heat transferred (J), m = mass (kg), L = specific latent heat (J/kg).
For water: J/kg (melting/freezing); J/kg (boiling/condensing).
Boiling vs. Evaporation
- Evaporation happens at the surface at any temperature.
- Boiling happens throughout the liquid at a specific temperature (100 °C for water at sea level).
- 1
Identify the phase change
Is energy absorbed (melting, boiling) or released (freezing, condensing)? - 2
Use Q = mL
Or Q = mcΔT for heating/cooling without a phase change. - 3
Remember: temperature is constant during the change
Do not include ΔT in the latent heat calculation.
How much energy is needed to melt 0.5 kg of ice at 0 °C? (L = 334 000 J/kg)
Real world: ice in a drink
Ice cubes in a drink absorb latent heat of fusion from the liquid: per kilogram of ice melted. During this phase change the temperature stays at 0°C — the ice keeps the drink cold while it melts, not before or after. This is why a drink with ice stays cold much longer than a pre-chilled drink without ice.
Real world: steam iron
A steam iron converts liquid water to steam (gas) by supplying latent heat of vaporisation. The steam condenses on fabric, releasing of energy that relaxes textile fibres. The large value of latent heat of vaporisation for water means the steam carries a lot of energy per kilogram — far more than hot water at the same temperature.
Real world: weather formation
When moist warm air rises, it cools and the water vapour condenses into tiny droplets (gas → liquid), forming clouds. The latent heat released during condensation warms the surrounding air, causing it to rise further and potentially triggering thunderstorms. Phase changes drive global weather patterns.
Practice Problems
What happens to the temperature of water while it is boiling?
Show answer
List the three states of matter in order of increasing particle kinetic energy at the same temperature.
Show answer
How much energy is released when 2 kg of steam condenses to water? (L = 2 260 000 J/kg)